Issue 14, 2003
From the journal:

Chemical Communications

A novel one-pot three-component tandem Michael/aldol/Horner–Wadsworth–Emmons (HWE) reaction of lithium alkylselenolates with 1-alkynylphosphine oxides and aldehydes: facile synthesis of selenium-substituted allenes†

Xian Huang*ab  and  Zheng-Chang Xionga  

* Corresponding authors

a Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou 310028, P. R. China

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

The one-pot tandem Michael/aldol/Horner–Wadsworth–Emmons (HWE) reaction of lithium alkylselenolates, 1-alkynylphosphine oxides and aldehydes in THF provides a new general access to selenium-substituted allenes with good to excellent yields.

Graphical abstract: A novel one-pot three-component tandem Michael/aldol/Horner–Wadsworth–Emmons (HWE) reaction of lithium alkylselenolates with 1-alkynylphosphine oxides and aldehydes: facile synthesis of selenium-substituted allenes

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Article information

DOI
https://doi.org/10.1039/B304527G
Article type
Communication
Submitted
25 Apr 2003
Accepted
20 May 2003
First published
11 Jun 2003

Chem. Commun., 2003, 1714-1715

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A novel one-pot three-component tandem Michael/aldol/Horner–Wadsworth–Emmons (HWE) reaction of lithium alkylselenolates with 1-alkynylphosphine oxides and aldehydes: facile synthesis of selenium-substituted allenes

X. Huang and Z. Xiong, Chem. Commun., 2003, 1714 DOI: 10.1039/B304527G

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