Issue 14, 2003
From the journal:

Chemical Communications

A heterobimetallic K2Ti2 complex incorporating two calix[5]arenes: A diverse array of metal–ligand interplay

Antonella J. Petrella,a   Nicholas K. Roberts,a   Donald C. Craig,a   Colin L. Rastonb  and  Robert N. Lamba  

a School of Chemical Sciences, University of New South Wales, Sydney, Australia
E-mail: r.lamb@unsw.edu.au

b School of Biomedical and Chemical Sciences, University of Western Australia, Crawley WA, Australia
E-mail: clraston@chem.uwa.edu.au

Abstract

Reaction of p-tBu-calix[5]arene with potassium metal in a mixture of methanol and THF followed by [Ti(acac)2(OPri)2] affords an unsymmetrical dimeric 1∶1 K/Ti complex built up from a central Ti–O–Ti core with each titanium(IV) centre octahedrally coordinated, bearing an acac and a calix[5]arene encapsulating a potassium ion.

Graphical abstract: A heterobimetallic K2Ti2 complex incorporating two calix[5]arenes: A diverse array of metal–ligand interplay

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Article information

DOI
https://doi.org/10.1039/B304449A
Article type
Communication
Submitted
24 Apr 2003
Accepted
23 May 2003
First published
18 Jun 2003

Chem. Commun., 2003, 1728-1729

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A heterobimetallic K2Ti2 complex incorporating two calix[5]arenes: A diverse array of metal–ligand interplay

A. J. Petrella, N. K. Roberts, D. C. Craig, C. L. Raston and R. N. Lamb, Chem. Commun., 2003, 1728 DOI: 10.1039/B304449A

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