Issue 15, 2003
From the journal:

Chemical Communications

Strong optical limiting capability of a triosmium cluster bonded indium porphyrin complex [(TPP)InOs3(μ-H)2(CO)9(μ-η2-C5H4N)]

Xinhua Zhong,a   Yaoyu Feng,*b   Say-Leong Ong,b   Jiangyong Hu,b   Wun-Jern Ngb  and  Zheming Wangc  

* Corresponding authors

a Department of Materials Science, National University of Singapore, Singapore 119260, Singapore

b Department of Civil Engineering, National University of Singapore, Singapore 119260, Singapore
E-mail: cvefyy@nus.edu.sg.
Fax: 65 6874 5266
Tel: 65 6874 5265

c State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, China

Abstract

The metal–metal bonded indium porphyrin–osmium cluster complex [(TPP)InOs3(μ-H)2(CO)9(μ-η2-C5H4N)] was first synthesized and characterized using the indium porphyrin hydride as the precursor. The complex has very good optical limiting performance with determined optical limiting threshold of 0.4 J cm−2.

Graphical abstract: Strong optical limiting capability of a triosmium cluster bonded indium porphyrin complex [(TPP)InOs3(μ-H)2(CO)9(μ-η2-C5H4N)]

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Article information

DOI
https://doi.org/10.1039/B304349E
Article type
Communication
Submitted
23 Apr 2003
Accepted
09 Jun 2003
First published
03 Jul 2003

Chem. Commun., 2003, 1882-1883

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Strong optical limiting capability of a triosmium cluster bonded indium porphyrin complex [(TPP)InOs3(μ-H)2(CO)9(μ-η2-C5H4N)]

X. Zhong, Y. Feng, S. Ong, J. Hu, W. Ng and Z. Wang, Chem. Commun., 2003, 1882 DOI: 10.1039/B304349E

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