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Issue 12, 2003
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Synthesis of ionisable [2 × 2] grid-type metallo-arrays and reversible protonic modulation of the optical properties of the [CoII4L4]8+ species

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Abstract

The new bis-hydrazone based ligands A and B form ionisable [2 × 2] grid-type transition metal complexes whose properties may be modulated by multiple protonation/deprotonation as shown by the reversible change in optical properties of the [CoII4L4]8+ complexes depending on their protonation state.

Graphical abstract: Synthesis of ionisable [2 × 2] grid-type metallo-arrays and reversible protonic modulation of the optical properties of the [CoII4L4]8+ species

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Publication details

The article was received on 08 Apr 2003, accepted on 29 Apr 2003 and first published on 16 May 2003


Article type: Communication
DOI: 10.1039/B303922F
Citation: Chem. Commun., 2003,0, 1338-1339

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    Synthesis of ionisable [2 × 2] grid-type metallo-arrays and reversible protonic modulation of the optical properties of the [CoII4L4]8+ species

    M. Ruben, J. Lehn and G. Vaughan, Chem. Commun., 2003, 0, 1338
    DOI: 10.1039/B303922F

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