Issue 13, 2003
From the journal:

Chemical Communications

Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex†

Hiroto Yoshida,*a   Yasuhito Yamaryo,a   Joji Ohshitaa  and  Atsutaka Kunai*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Hiroshima Univerisity, Higashi-Hiroshima 739-8527, Japan
E-mail: yhiroto@hiroshima-u.ac.jp, akunai@hiroshima-u.ac.jp
Fax: +81-824-24-5494

Abstract

Oxidative homocoupling reaction of aryl- or alkynylsilanes was found to proceed without any added activators using a catalytic amount of a palladium–1,3-bis(diphenylphosphino)propane complex, affording the corresponding biaryls or 1,3-diynes in modest to excellent yields.

Graphical abstract: Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex

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Article information

DOI
https://doi.org/10.1039/B303852A
Article type
Communication
Submitted
07 Apr 2003
Accepted
02 May 2003
First published
21 May 2003

Chem. Commun., 2003, 1510-1511

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Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex

H. Yoshida, Y. Yamaryo, J. Ohshita and A. Kunai, Chem. Commun., 2003, 1510 DOI: 10.1039/B303852A

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