Issue 14, 2003
From the journal:

Chemical Communications

The use of a germene for the synthesis of esters of α-germyl-substituted α-amino acid and α-aminophosphonic acid†

S. Ech-Cherif El Kettani,ab   J. Escudié,b   C. Couret,b   H. Ranaivonjatovo,b   M. Lazraq,ab   M. Soufiaoui,c   H. Gornitzkab  and  G. Cretiu Nemesbd  

a Université Sidi Mohamed Ben Abdellah, Faculté des Sciences Dhar El Mehrez, BP 1796 Atlas-Fès, Morocco

b Hétérochimie Fondamentale et Appliquée, UMR 5069, Université Paul Sabatier, 118 Route de Narbonne, 31062, Toulouse Cedex 04, France

c Université Mohamed V, Agdal, Faculté des Sciences, Avenue Ibn Batouta, Rabat, Morocco

d Universitatea Babes-Bolyai Cluj, Facultatea de Chimie si Inginerie Chimica, Kogalniceanu nr. 1, RO-3400, Cluj-Napoca, Romania

Abstract

The first α-germyl-substituted α-amino ester and α-germyl-substituted α-aminophosphonic ester have been synthesized by a one-pot reaction between the germene Mes2Ge[double bond, length as m-dash]CR2 (CR2 = fluorenylidene) and the iminoester or iminophosphonate Ph(H)C[double bond, length as m-dash]NCH2–Y (Y = COOMe, P(O)(OEt)2).

Graphical abstract: The use of a germene for the synthesis of esters of α-germyl-substituted α-amino acid and α-aminophosphonic acid

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Article information

DOI
https://doi.org/10.1039/B303661H
Article type
Communication
Submitted
01 Apr 2003
Accepted
20 May 2003
First published
05 Jun 2003

Chem. Commun., 2003, 1662-1663

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The use of a germene for the synthesis of esters of α-germyl-substituted α-amino acid and α-aminophosphonic acid

S. Ech-Cherif El Kettani, J. Escudié, C. Couret, H. Ranaivonjatovo, M. Lazraq, M. Soufiaoui, H. Gornitzka and G. Cretiu Nemes, Chem. Commun., 2003, 1662 DOI: 10.1039/B303661H

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