Issue 14, 2003
From the journal:

Chemical Communications

Primary charge separation in photoinduced multielectron storage systems. A dinuclear ruthenium(ii) species featuring a charge-separated state with a lifetime of 1.3 µs†

Claudio Chiorboli,ac   Sandro Fracasso,b   Franco Scandola,abc   Sebastiano Campagna,d   Scolastica Serroni,d   Rama Kondurie  and  Frederick M. MacDonnelle  

a ISOF-CNR Sezione di Ferrara, Via L. Borsari 46, 44100 Ferrara, Italy
E-mail: chc@unife.it

b Dipartimento di Chimica, Via L. Borsari 46, 44100 Ferrara, Italy
E-mail: snf@unife.it

c INSTM UdR Ferrara, Via L. Borsari 46, 44100 Ferrara, Italy

d Dipartimento di Chimica Inorganica, Chimica Analitica & Chimica Fisica, Università di Messina and INSTM UdR Messina, Via Sperone 31, 98166 Messina, Italy
E-mail: photochem@chem.unime.it

e Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, TX, USA
E-mail: macdonn@uta.edu

Abstract

The primary photoinduced charge separation and recombination processes occurring in a dinuclear Ru(II) complex capable to perform multielectron storage upon light excitation have been studied in different solvents: the charge-separated state obtained in dichloromethane is, to the best of our knowledge, the longest-lived ever reported for a ruthenium polypyridine complex.

Graphical abstract: Primary charge separation in photoinduced multielectron storage systems. A dinuclear ruthenium(ii) species featuring a charge-separated state with a lifetime of 1.3 µs

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Article information

DOI
https://doi.org/10.1039/B302962J
Article type
Communication
Submitted
18 Mar 2003
Accepted
03 Apr 2003
First published
06 Jun 2003

Chem. Commun., 2003, 1658-1659

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Primary charge separation in photoinduced multielectron storage systems. A dinuclear ruthenium(II) species featuring a charge-separated state with a lifetime of 1.3 µs

C. Chiorboli, S. Fracasso, F. Scandola, S. Campagna, S. Serroni, R. Konduri and F. M. MacDonnell, Chem. Commun., 2003, 1658 DOI: 10.1039/B302962J

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