Issue 12, 2003
From the journal:

Chemical Communications

Solid state structures of pentacoordinated λ3-iodanes with a trigonal bipyramidal geometry: synthesis of diphenyl- and alkynyl(phenyl)-λ3-iodane complexes with 1,10-phenanthroline

Masahito Ochiai,*a   Takashi Suefuji,a   Kazunori Miyamotoa  and  Motoo Shirob  

* Corresponding authors

a Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan
E-mail: mochiai@ph2.tokushima-u.ac.jp;
Fax: +81 88 633 9504
Tel: +81 88 633 7281

b Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo 196-8666, Japan

Abstract

The single crystal X-ray structure of the supramolecular complex formed between diphenyl-λ3-iodane (Ph2IBF4) or 1-alkynyl(phenyl)-λ3-iodane [ButCCI(Ph)BF4] and 1,10-phenanthroline indicates a hitherto unknown distorted trigonal bipyramidal geometry around iodine(III), in which 1,10-phenanthroline acts as a bidentate ligand and occupies equatorial sites.

Graphical abstract: Solid state structures of pentacoordinated λ3-iodanes with a trigonal bipyramidal geometry: synthesis of diphenyl- and alkynyl(phenyl)-λ3-iodane complexes with 1,10-phenanthroline

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Article information

DOI
https://doi.org/10.1039/B302579A
Article type
Communication
Submitted
06 Mar 2003
Accepted
24 Apr 2003
First published
16 May 2003

Chem. Commun., 2003, 1438-1439

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Solid state structures of pentacoordinated λ3-iodanes with a trigonal bipyramidal geometry: synthesis of diphenyl- and alkynyl(phenyl)-λ3-iodane complexes with 1,10-phenanthroline

M. Ochiai, T. Suefuji, K. Miyamoto and M. Shiro, Chem. Commun., 2003, 1438 DOI: 10.1039/B302579A

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