Issue 13, 2003
From the journal:

Chemical Communications

Tuning of ruthenium N-heterocyclic carbenecatalysts for ATRP†

Lionel Delaude,a   Sébastien Delfosse,a   Aurore Richel,a   Albert Demonceau*a  and  Alfred F. Noelsa  

* Corresponding authors

a Laboratory of Macromolecular Chemistry and Organic Catalysis, University of Liège, Sart-Tilman (B.6a), B-4000 Liège, Belgium
E-mail: A.Demonceau@ulg.ac.be.
Fax: ++32/4 366 3497
Tel: ++32/4 366 3495

Abstract

Depending on the substituents, R1 and R2, ruthenium(II)–p-cymene complexes bearing N-heterocyclic carbene ligands are either efficient catalysts for the well-controlled atom transfer radical polymerisation of methyl methacrylate and styrene, or promote a redox-initiated free-radical process.

Graphical abstract: Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP

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Article information

DOI
https://doi.org/10.1039/B301733H
Article type
Communication
Submitted
15 Feb 2003
Accepted
02 May 2003
First published
30 May 2003

Chem. Commun., 2003, 1526-1527

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Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP

L. Delaude, S. Delfosse, A. Richel, A. Demonceau and A. F. Noels, Chem. Commun., 2003, 1526 DOI: 10.1039/B301733H

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