Issue 9, 2003

Fraction of the CoMoS phases accessible to NO in Co–Mo hydrodesulfurization catalysts

Abstract

It is established by using Co–Mo model sulfide catalysts, XAFS and FTIR that Co atoms constituting CoMoS phases are not oxidized by NO adsorption and that only 55% of the CoMoS phases is susceptible to NO adsorption even at the maximum coordinative unsaturation attainable under usual HDS reaction conditions (623–673 K).

Graphical abstract: Fraction of the CoMoS phases accessible to NO in Co–Mo hydrodesulfurization catalysts

Article information

Article type
Communication
Submitted
06 Feb 2003
Accepted
19 Mar 2003
First published
07 Apr 2003

Chem. Commun., 2003, 1086-1087

Fraction of the CoMoS phases accessible to NO in Co–Mo hydrodesulfurization catalysts

Y. Okamoto, M. Kawano and T. Kubota, Chem. Commun., 2003, 1086 DOI: 10.1039/B301487H

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