Issue 9, 2003
From the journal:

Chemical Communications

Inhibited chelation in the new γ-phosphino-β-diketiminate to give phosphine → arsine coordination

Paul J. Ragogna,a   Neil Burford,*a   Mark D'eona  and  R. McDonaldb  

* Corresponding authors

a Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3, Canada
E-mail: Neil.Burford@dal.ca
Fax: 1-902-494-1310
Tel: 1-902-494-3190

b Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada
E-mail: Bob.McDonald@ualberta.ca
Fax: 1-780-492-8231
Tel: 1-780-492-2485

Abstract

A γ-diphenylphosphino-β-diketimine has been synthesised and the 31P NMR handle allows for in situ analysis of reaction mixtures revealing unprecedented reactivity with AsCl3 to give a novel phosphinoarsine intramolecular coordination complex.

Graphical abstract: Inhibited chelation in the new γ-phosphino-β-diketiminate to give phosphine → arsine coordination

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Article information

DOI
https://doi.org/10.1039/B301333B
Article type
Communication
Submitted
04 Feb 2003
Accepted
10 Mar 2003
First published
31 Mar 2003

Chem. Commun., 2003, 1052-1053

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Inhibited chelation in the new γ-phosphino-β-diketiminate to give phosphine → arsine coordination

P. J. Ragogna, N. Burford, M. D'eon and R. McDonald, Chem. Commun., 2003, 1052 DOI: 10.1039/B301333B

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