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Why [CpW(CO)3]+ reduces H2 to dihydride†
Abstract
The [CpW(CO)3]+ complex, with three π acceptor ligands and a positive charge, is shown to have an unexpected reducing ability towards H2 because of a low lying triplet state energy.
![Graphical abstract: Why [CpW(CO)3]+ reduces H2 to dihydride](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B301245J&imageInfo.ImageIdentifier.Year=2003)
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Supplementary files
Article information
- Article type
- Communication
- Submitted
- 30 Jan 2003
- Accepted
- 17 Feb 2003
- First published
- 28 Feb 2003
Chem. Commun., 2003, 850-851
Permissions
Why [CpW(CO)3]+ reduces H2 to dihydride
H. Lesnard, I. Demachy, Y. Jean and A. Lledos, Chem. Commun., 2003, 850 DOI: 10.1039/B301245J
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