Issue 6, 2003
From the journal:

Chemical Communications

A novel access to 3-aryl-2-norbornyl cation

Mariella Mella,a   Silvia Esposti,a   Maurizio Fagnonia  and  Angelo Albinia  

a Department of Organic Chemistry, University of Pavia, via Taramelli 10, 27100 Pavia, Italy
E-mail: albini@chifis. unipv.it
Fax: 39 0382 507323
Tel: 39 0382 507316

Abstract

A novel access to a 2-norbornyl cation under mild, non acidic conditions is found in the addition of photochemically generated 4-dimethylaminophenyl cation to 2-norbornene. Deprotonation to nortricyclene or nucleophile addition ensue depending on the solvent characteristics.

Graphical abstract: A novel access to 3-aryl-2-norbornyl cation

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Article information

DOI
https://doi.org/10.1039/B300839H
Article type
Communication
Submitted
21 Jan 2003
Accepted
12 Feb 2003
First published
25 Feb 2003

Chem. Commun., 2003, 738-739

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A novel access to 3-aryl-2-norbornyl cation

M. Mella, S. Esposti, M. Fagnoni and A. Albini, Chem. Commun., 2003, 738 DOI: 10.1039/B300839H

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