Issue 7, 2003

Deuterium isotope effect on the solid-state thermal isomerization of photo-coloured cis-keto species of N-salicylideneaniline

Abstract

Deuterium isotope kinetic effect in the solid state was observed by using thermal fading reaction of photo-coloured species derived from N-salicylideneaniline deuterohydroxyl derivative; thus, the existence of a cis-keto form in the photo-coloured Schiff base crystals was suggested experimentally along with 6-methyl-substitution effect on the stability of the photoproduct.

Graphical abstract: Deuterium isotope effect on the solid-state thermal isomerization of photo-coloured cis-keto species of N-salicylideneaniline

Article information

Article type
Communication
Submitted
21 Jan 2003
Accepted
20 Feb 2003
First published
05 Mar 2003

Chem. Commun., 2003, 870-871

Deuterium isotope effect on the solid-state thermal isomerization of photo-coloured cis-keto species of N-salicylideneaniline

K. Amimoto, H. Kanatomi, A. Nagakari, H. Fukuda, H. Koyama and T. Kawato, Chem. Commun., 2003, 870 DOI: 10.1039/B300830D

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