Issue 7, 2003
From the journal:

Chemical Communications

A novel imidazolate-bridged heterodinuclear Cu(ii)Zn(ii) complex derived from a unique macrocyclic ligand with two hydroxyethyl pendants†

Shu-an Li,a   Dong-feng Li,*a   De-xi Yang,a   Yi-zhi Li,a   Jin Huang,a   Kai-bei Yub  and  (the late)Wen-xia Tang*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, China
E-mail: chem1121@nju.edu.cn
Fax: +86-025-3314502

b Analysis Center, Chengdu Branch of Chinese Academy of Sciences, Chengdu 610041, China

Abstract

[(CuimZnL−2H)(CuimZnL−H)](ClO4)3, the first imidazolate-bridged Cu(II)–Zn(II) complex of a unique single macrocyclic ligand with two flexible hydroxyethyl pendants, L (L = 3,6,9,16,19,22-hexaaza-6,19-bis(2-hydroxyethyl)tricyclo[22.2.2.211,14]triaconta-1,11,13,24,27,29-hexaene) has been obtained, in which the macrocyclic ligand with two hydroxyethyl arms possesses a markedly different conformation compared to its dicopper analogue.

Graphical abstract: A novel imidazolate-bridged heterodinuclear Cu(ii)Zn(ii) complex derived from a unique macrocyclic ligand with two hydroxyethyl pendants

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Article information

DOI
https://doi.org/10.1039/B300013C
Article type
Communication
Submitted
03 Jan 2003
Accepted
20 Feb 2003
First published
05 Mar 2003

Chem. Commun., 2003, 880-881

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A novel imidazolate-bridged heterodinuclear Cu(II)Zn(II) complex derived from a unique macrocyclic ligand with two hydroxyethyl pendants

S. Li, D. Li, D. Yang, Y. Li, J. Huang, K. Yu and W. Tang, Chem. Commun., 2003, 880 DOI: 10.1039/B300013C

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