First example of a Sn–C bond cleaved product in the reaction of Ph3SnOSnPh3 with carboxylic acids. 3D-Supramolecular network formation in the X-ray crystal structure of [Ph2Sn(OH)OC(O)(Rf)]2, Rf = 2,4,6-(CF3)3C6H2
Abstract
A 1∶2 reaction of Ph3SnOSnPh31 with RfCOOH 2 leads to the formation of [Ph2Sn(OH)OC(O)(Rf)]23, by means of a facile Sn–C bond cleavage process.