Issue 5, 2003
From the journal:

Chemical Communications

Room-temperature heterogeneous hydroxylation of phenol with hydrogen peroxide over Fe2+, Co2+ ion-exchanged Naβ zeolite

Jun Wang,ab   Jung-Nam Park,a   Xian-Yong Weiac  and  Chul Wee Lee*a  

* Corresponding authors

a Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology, P.O.Box 107, Yusung, Daejeon, Korea
E-mail: chulwee@pado.krict.re.kr
Fax: 82 42 860 7388
Tel: 82 42 860 7381

b Department of Chemical Engineering, Nanjing University of Technology, Nanjing, China

c School of Chemical Engineering, China University of Mining and Technology, Xuzhou, China

Abstract

Ion-exchanged Naβ zeolite with Fe2+ and Co2+ cations shows high catalytic activity at room temperature in phenol hydroxylation with H2O2, where the conversion of phenol is ca. 21% and the selectivity of benzoquinone is below 3% at a molar ratio of phenol to H2O2 of 3 in the starting aqueous reaction medium.

Graphical abstract: Room-temperature heterogeneous hydroxylation of phenol with hydrogen peroxide over Fe2+, Co2+ ion-exchanged Naβ zeolite

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Article information

DOI
https://doi.org/10.1039/B212296K
Article type
Communication
Submitted
13 Dec 2002
Accepted
27 Jan 2003
First published
06 Feb 2003

Chem. Commun., 2003, 628-629

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Room-temperature heterogeneous hydroxylation of phenol with hydrogen peroxide over Fe2+, Co2+ ion-exchanged Naβ zeolite

J. Wang, J. Park, X. Wei and C. W. Lee, Chem. Commun., 2003, 628 DOI: 10.1039/B212296K

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