Issue 2, 2003
From the journal:

Chemical Communications

Unexpected isolation, and structural characterization, of a β-hydrogen-containing σ-alkylpalladium halide complex in the course of an intramolecular Heck reaction. Synthesis of polycyclic isoquinoline derivatives†

Blandine Clique,a   Charles-Henry Fabritius,a   Cédric Couturier,a   Nuno Monteiro*a  and  Geneviève Balme*a  

* Corresponding authors

a Laboratoire de Chimie Organique 1, CNRS UMR 5622, Université Claude Bernard, Lyon I, CPE. 43, Bd du 11 Novembre 1918, Villeurbanne, France
E-mail: balme@univ-lyon1.fr

Abstract

The isolation of a stable β-hydrogen-containing R-PdLn-X complex (R = alkyl; X = halide) issued from a Heck reaction is reported together with some aspects of its reactivity.

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Article information

DOI
https://doi.org/10.1039/B211856B
Article type
Communication
Submitted
28 Nov 2002
Accepted
06 Dec 2002
First published
19 Dec 2002

Chem. Commun., 2003, 272-273

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Unexpected isolation, and structural characterization, of a β-hydrogen-containing σ-alkylpalladium halide complex in the course of an intramolecular Heck reaction. Synthesis of polycyclic isoquinoline derivatives

B. Clique, C. Fabritius, C. Couturier, N. Monteiro and G. Balme, Chem. Commun., 2003, 272 DOI: 10.1039/B211856B

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