Issue 3, 2003
From the journal:

Chemical Communications

Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product†

Todd C. Harrop,a   Marilyn M. Olmsteadb  and  Pradip K. Mascharak*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064

b Department of Chemistry, University of California, Davis, CA 95616

Abstract

A (μ-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.

Graphical abstract: Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product

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Article information

DOI
https://doi.org/10.1039/B211395N
Article type
Communication
Submitted
18 Nov 2002
Accepted
07 Dec 2002
First published
14 Jan 2003

Chem. Commun., 2003, 410-411

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Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product

T. C. Harrop, M. M. Olmstead and P. K. Mascharak, Chem. Commun., 2003, 410 DOI: 10.1039/B211395N

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