Issue 4, 2003
From the journal:

Chemical Communications

Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group†

Masakatsu Matsumoto,*a   Toshiyuki Mizunoa  and  Nobuko Watanabea  

* Corresponding authors

a Department of Materials Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa, Japan
E-mail: matsumo@chem.kanagawa-u.ac.jp
Fax: +81-463-59-4111
Tel: +81-463-58-9684

Abstract

A new type of dioxetane bearing a 3-(cyanomethyl)phenyl (1a), 3-(methoxycarbonylmethyl)phenyl (1b), 3-(benzoylmethyl)phenyl (1c), or 3-[cyano(methoxycarbonyl)methyl]phenyl group (1d) decomposed through an intermediary dioxetane bearing a benzylic carbanion to afford crimson to yellow light on treatment with TBAF in DMSO.

Graphical abstract: Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group

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Article information

DOI
https://doi.org/10.1039/B210857G
Article type
Communication
Submitted
06 Nov 2002
Accepted
13 Jan 2003
First published
27 Jan 2003

Chem. Commun., 2003, 482-483

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Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group

M. Matsumoto, T. Mizuno and N. Watanabe, Chem. Commun., 2003, 482 DOI: 10.1039/B210857G

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