Issue 3, 2003
From the journal:

Chemical Communications

The anionic thia-Fries rearrangement of aryl triflates

Jonathan P. H. Charmant,a   Alan M. Dykeb  and  Guy C. Lloyd-Jones*b  

* Corresponding authors

a Structural Chemistry Laboratory, School of Chemistry, Cantock’s Close, Bristol, UK

b Bristol Centre for Organometallic Catalysis, Cantock’s Close, Bristol, UK
E-mail: guy.lloyd-jones@bris.ac.uk
Fax: 44 117 929 861
Tel: 44 117 928 8165

Abstract

Aryl triflates undergo LDA-mediated rearrangement to generate o-hydroxyaryl trifluoromethylsulfones. In some cases, partitioning between rearrangement and aryne generation can be controlled.

Graphical abstract: The anionic thia-Fries rearrangement of aryl triflates

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Article information

DOI
https://doi.org/10.1039/B210648E
Article type
Communication
Submitted
30 Oct 2002
Accepted
17 Dec 2002
First published
14 Jan 2003

Chem. Commun., 2003, 380-381

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The anionic thia-Fries rearrangement of aryl triflates

J. P. H. Charmant, A. M. Dyke and G. C. Lloyd-Jones, Chem. Commun., 2003, 380 DOI: 10.1039/B210648E

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