Issue 4, 2003
From the journal:

Chemical Communications

A convenient stereoselective synthesis of trifluoromethyl-substituted polyfunctionalized cyclopropane: synthesis of (±)-trans-trifluoronorcoronamic acid

Biao Jiang,*a   Fangjiang Zhanga  and  Wennan Xionga  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai, P. R. China
E-mail: jiangb@pub.sioc.ac.cn
Fax: +86-21-64166128
Tel: +86-2164163300

Abstract

Trifluoromethylated polyfunctionalized cyclopropanes were obtained in high stereoselectivity by reacting 2-bromo-3,3,3-trifluoropropene (BrTFP) with active methylenes. This novel method was further applied to the synthesis of (±)-trans-trifluoronorcoronamic acid.

Graphical abstract: A convenient stereoselective synthesis of trifluoromethyl-substituted polyfunctionalized cyclopropane: synthesis of (±)-trans-trifluoronorcoronamic acid

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Article information

DOI
https://doi.org/10.1039/B210642F
Article type
Communication
Submitted
30 Oct 2002
Accepted
14 Jan 2003
First published
29 Jan 2003

Chem. Commun., 2003, 536-537

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A convenient stereoselective synthesis of trifluoromethyl-substituted polyfunctionalized cyclopropane: synthesis of (±)-trans-trifluoronorcoronamic acid

B. Jiang, F. Zhang and W. Xiong, Chem. Commun., 2003, 536 DOI: 10.1039/B210642F

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