Issue 1, 2003
From the journal:

Chemical Communications

η6-Arene complexes of Ni(ii), efficient catalysts for 1,3-butadiene and styrene polymerization†

Juan Cámpora,*a   María del Mar Conejo,a   Manuel L. Reyes,a   Kurt Mereiterb  and  Elisa Passagliac  

* Corresponding authors

a Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas, Universidad de Sevilla, c/ Américo Vespucio s/n, Isla de la Cartuja, Sevilla, Spain
E-mail: campora@iiq.csic.es (for J. Cámpora)

b Department of Chemistry, Vienna University of Technology, Getreidemarkt 9/164, Vienna, Austria
E-mail: Kurt.Mereiter@tuwien.ac.at

c Dipartimento di Chimica e Chimica Industriale, Università di Pisa, CNR-ICCOM Sezione di Pisa, via Risorgimento 35, Pisa, Italy
E-mail: elpas@dcci.unipi.it

Abstract

A simple procedure for the preparation of cationic arene complexes of Ni(II) of composition [Ni(η6-ArX)(η3-C3H5)]+[BAr′4]− (X = OH, H) is reported. These compounds are shown to behave as highly active catalysts for the polymerization of 1,3-butadiene and styrene.

Graphical abstract: η6-Arene complexes of Ni(ii), efficient catalysts for 1,3-butadiene and styrene polymerization

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Article information

DOI
https://doi.org/10.1039/B209838E
Article type
Communication
Submitted
08 Oct 2002
Accepted
11 Nov 2002
First published
26 Nov 2002

Chem. Commun., 2003, 78-79

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η6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization

J. Cámpora, M. del Mar Conejo, M. L. Reyes, K. Mereiter and E. Passaglia, Chem. Commun., 2003, 78 DOI: 10.1039/B209838E

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