Issue 1, 2003
From the journal:

Chemical Communications

Stabilization of the previously unknown tautomer HP(OH)2 of hypophosphorous acid as ligand; preparation of [W3(Ni(HP(OH)2))Q4(H2O)9]4+(Q = S, Se) complexes†

Maxim N. Sokolov,*a   Rita Hernández-Molina,b   William Clegg,c   Vladimir P. Fedina  and  Alfredo Mederosb  

* Corresponding authors

a Institute of Inorganic Chemistry SB RAS, pr. Lavrentyeva 3, Novosibirsk, Russia
E-mail: cluster@che.nsk.su
Fax: (+7)3832-344489

b Department of Inorganic Chemistry, University of La Laguna, 38200 La Laguna, Tenerife, Spain

c School of Natural Sciences (Chemistry), University of Newcastle upon Tyne, Newcastle upon Tyne, UK

Abstract

Bis(hydroxy)phosphine, the isomer of hypophosphorous acid which remained elusive for a long time, coordinates to the Ni site of heterometallic clusters with a W3NiQ4 core (Q = S, Se) to give [W3(Ni(HP(OH)2))Q4(H2O)9]4+ (Q = S, Se).

Graphical abstract: Stabilization of the previously unknown tautomer HP(OH)2 of hypophosphorous acid as ligand; preparation of [W3(Ni(HP(OH)2))Q4(H2O)9]4+(Q = S, Se) complexes

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Article information

DOI
https://doi.org/10.1039/B209792C
Article type
Communication
Submitted
08 Oct 2002
Accepted
18 Nov 2002
First published
02 Dec 2002

Chem. Commun., 2003, 140-141

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Stabilization of the previously unknown tautomer HP(OH)2 of hypophosphorous acid as ligand; preparation of [W3(Ni(HP(OH)2))Q4(H2O)9]4+(Q = S, Se) complexes

M. N. Sokolov, R. Hernández-Molina, W. Clegg, V. P. Fedin and A. Mederos, Chem. Commun., 2003, 140 DOI: 10.1039/B209792C

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