Issue 3, 2003
From the journal:

Chemical Communications

Chemical and transient spectroscopic evidence for C2–C3 cleavage of 2,3-diaryloxetane radical cations

Miguel A. Miranda*a  and  M. Angeles Izquierdoa  

* Corresponding authors

a Dpto. de Química de la Universidad Politécnica de Valencia, Camino de Vera s/n, Apdo. 22012, Valencia, Spain
E-mail: mmiranda@qim.upv.es
Fax: 34 963877349
Tel: 34 963877807

Abstract

Electron transfer cycloreversion of the methoxy substituted oxetane 1b results in the production of trans-anethole and benzaldehyde through C2–C3 bond cleavage. trans-Anethole radical cation has been detected as transient intermediate by laser flash photolysis.

Graphical abstract: Chemical and transient spectroscopic evidence for C2–C3 cleavage of 2,3-diaryloxetane radical cations

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Article information

DOI
https://doi.org/10.1039/B209500A
Article type
Communication
Submitted
27 Sep 2002
Accepted
13 Dec 2002
First published
13 Jan 2003

Chem. Commun., 2003, 364-365

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Chemical and transient spectroscopic evidence for C2–C3 cleavage of 2,3-diaryloxetane radical cations

M. A. Miranda and M. A. Izquierdo, Chem. Commun., 2003, 364 DOI: 10.1039/B209500A

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