Issue 1, 2003

Novel addition reactions of titanacycle phosphonates by tuning of Ti(O-i-Pr)4/2i-PrMgCl

Abstract

Di- or tri-substituted vinylphosphonates, 25, can be obtained in a highly regio- and stereoselective manner from 1-alkynylphosphonates, by manipulation of Ti(O-i-Pr)4/2i-PrMgCl.

Graphical abstract: Novel addition reactions of titanacycle phosphonates by tuning of Ti(O-i-Pr)4/2i-PrMgCl

Supplementary files

Article information

Article type
Communication
Submitted
19 Sep 2002
Accepted
13 Nov 2002
First published
25 Nov 2002

Chem. Commun., 2003, 58-59

Novel addition reactions of titanacycle phosphonates by tuning of Ti(O-i-Pr)4/2i-PrMgCl

A. A. A. Quntar and M. Srebnik, Chem. Commun., 2003, 58 DOI: 10.1039/B209149F

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