Issue 2, 2002

Determination of the rate constants of the addition of primary alkyl radicals to allylstannanes

Abstract

The rate constants and the activation parameters of the addition of primary alkyl radicals to allyldibutyl-4,7,10-trioxaundecylstannane 1 and (2-ethoxycarbonylprop-2-enyl)dibutyl-4,7,10-trioxaundecylstannane 2 were determined by studying their respective free radical reactions with (2-bromo-1,1-dimethylethyl)benzene and 6-bromohex-1-ene at different temperatures.

Graphical abstract: Determination of the rate constants of the addition of primary alkyl radicals to allylstannanes

Article information

Article type
Paper
Submitted
05 Oct 2001
Accepted
27 Nov 2001
First published
14 Jan 2002

J. Chem. Soc., Perkin Trans. 2, 2002, 247-250

Determination of the rate constants of the addition of primary alkyl radicals to allylstannanes

F. Ferkous, M. Degueil-Castaing, H. Deleuze and B. Maillard, J. Chem. Soc., Perkin Trans. 2, 2002, 247 DOI: 10.1039/B108875K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements