Issue 23, 2002

Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors

Abstract

Triols containing three secondary hydroxy groups were rearranged using either (i) toluene-p-sulfonic acid or (ii) trimethyl orthoacetate–pyridinium toluene-p-sulfonate followed by toluene-p-sulfonic acid

Graphical abstract: Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors

Supplementary files

Article information

Article type
Paper
Submitted
03 Sep 2002
Accepted
02 Oct 2002
First published
07 Nov 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 2652-2662

Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors

D. House, F. Kerr and S. Warren, J. Chem. Soc., Perkin Trans. 1, 2002, 2652 DOI: 10.1039/B208558E

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