The metal-mediated addition of a range of nucleophiles to several bridged η6-chromiumtricarbonyl complexes has been demonstrated for the first time. The reaction proceeds in regio- and stereoselective fashion and in fair to good yield. The new reaction was applied to the synthesis of an advanced intermediate towards anatoxin-a.
R. E. J. Beckwith, M. B. Gravestock and N. S. Simpkins, J. Chem. Soc., Perkin Trans. 1, 2002, 2352 DOI: 10.1039/B207708F
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