Issue 15, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

C-Glycoside formation via Lewis acid promoted reaction of O-glycosylimidates with pyrroles

David J. Armitt,ab   Martin G. Banwell,*a   Craig Freemanb  and  Christopher R. Parishb  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia
E-mail: mgb@rsc.anu.edu.au

b John Curtin School of Medical Research, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia

Abstract

O-Glycosylimidates such as 1 react with pyrroles in the presence of BF3·Et2O to give C-glycosides, e.g.2, that are readily elaborated to congeners such as 12 and 13.

Graphical abstract: C-Glycoside formation via Lewis acid promoted reaction of O-glycosylimidates with pyrroles

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Article information

DOI
https://doi.org/10.1039/B205690A
Article type
Communication
Submitted
12 Jun 2002
Accepted
26 Jun 2002
First published
09 Jul 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 1743-1745

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C-Glycoside formation via Lewis acid promoted reaction of O-glycosylimidates with pyrroles

D. J. Armitt, M. G. Banwell, C. Freeman and C. R. Parish, J. Chem. Soc., Perkin Trans. 1, 2002, 1743 DOI: 10.1039/B205690A

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