Improving epoxide production using Ti-UVM-7 porous nanosized catalysts

Jamal El Haskouri; David Ortiz de Zárate; Francisco Pérez-Pla; Antonio Cervilla; Carmen Guillem; Julio Latorre; M. Dolores Marcos; Aurelio Beltrán; Daniel Beltrán; Pedro Amorós

doi:10.1039/B205856C

Improving epoxide production using Ti-UVM-7 porous nanosized catalysts†

Jamal El Haskouri,^a David Ortiz de Zárate,^a Francisco Pérez-Pla,^b Antonio Cervilla,^a Carmen Guillem,^a Julio Latorre,^a M. Dolores Marcos,^c Aurelio Beltrán,^a Daniel Beltrán^a and Pedro Amorós*^a

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^a Institut de Ciència dels Materials (ICMUV), Universitat de València, P. O. Box 2085, València, Spain
E-mail: pedro.amoros@uv.es
Fax: +34 96 3983633
Tel: +34 96 3983617

^b Departament de Química Física, Universitat de València, Dr. Moliner 50, Burjassot (Valencia), Spain

^c Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, Valencia, Spain

Abstract

Nanosized Ti-UVM-7 materials with a hierarchical system of pores at two different length scales have been prepared through a one-pot procedure by using a simple template agent; the catalytic activity and selectivity of the resulting materials in bulky olefin epoxidation by organic peroxides are the highest reported to date.

New Journal of Chemistry

Improving epoxide production using Ti-UVM-7 porous nanosized catalysts†

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Improving epoxide production using Ti-UVM-7 porous nanosized catalysts

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