Issue 9, 2002
From the journal:

New Journal of Chemistry

Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SC CO2/[bmim][PF6] mixed solvent

Zhenshan Hou,a   Buxing Han,*a   Liang Gao,a   Tao Jiang,a   Zhimin Liu,a   Yanhong Chang,a   Xiaogang Zhanga  and  Jun Hea  

* Corresponding authors

a The Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, P. R. China
E-mail: hanbx@infoc3.icas.ac.cn
Fax: +86-10-62569373
Tel: +86-10-62562821

Abstract

Oxidation of 1-hexene by molecular oxygen is conducted in 1-n-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6], supercritical (SC) CO2, SC CO2/[bmim][PF6] mixed solvent, and in the absence of solvent. The selectivity to the desired product 2-hexanone is much higher when the reaction is carried out in the mixed solvent, and the catalysts is more stable in SC CO2/[bmim][PF6] mixed solvent than in SC CO2.

Graphical abstract: Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SC CO2/[bmim][PF6] mixed solvent

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B201997C
Article type
Paper
Submitted
26 Feb 2002
Accepted
02 Jul 2002
First published
19 Jul 2002

New J. Chem., 2002,26, 1246-1248

Permissions

Request permissions

Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SC CO2/[bmim][PF6] mixed solvent

Z. Hou, B. Han, L. Gao, T. Jiang, Z. Liu, Y. Chang, X. Zhang and J. He, New J. Chem., 2002, 26, 1246 DOI: 10.1039/B201997C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements