Issue 6, 2002
From the journal:

New Journal of Chemistry

Syntheses of new hexacoordinate germanium(IV) complexes. Crystal structures and properties of [GeCl4(TMEDA)] and [GeCl2(N3)2(TMEDA)]

Jolanta Ejfler,a   Slawomir Szafert,a   Haijun Jiaob  and  Piotr Sobota*a  

* Corresponding authors

a Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie, Wrocław, Poland

b Institut für Organische Chemie, Friedrich-Alexander Universität Erlangen-Nürnberg, Henkestrasse 42, Erlangen, Germany

Abstract

The simple high-yield syntheses and some characterization of new hexacoordinate [GeCl4(TMEDA)] (1) and [GeCl2(N3)2(TMEDA)] (2) are reported. The crystal structures of neutral 1 and 2 are described. Some electronic, geometrical, and thermodynamic features of 1 and 2 were computationally investigated at the B3LYP density functional level of theory.

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Article information

DOI
https://doi.org/10.1039/B110770B
Article type
Paper
Submitted
22 Nov 2001
Accepted
25 Jan 2002
First published
07 Jun 2002

New J. Chem., 2002,26, 803-805

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Syntheses of new hexacoordinate germanium(IV) complexes. Crystal structures and properties of [GeCl4(TMEDA)] and [GeCl2(N3)2(TMEDA)]

J. Ejfler, S. Szafert, H. Jiao and P. Sobota, New J. Chem., 2002, 26, 803 DOI: 10.1039/B110770B

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