Issue 1, 2002
From the journal:

New Journal of Chemistry

Hetero-binuclear complexes containing a Ru0 → Mn+ bond bridged by P,N-phosphine ligands: convenient synthesis of tridentate organometallic trans-Ru(CO)3(L)2  (L = phosphine bearing an N-donor substituent) ligands

Hai-Bin Song,a   Zheng-Zhi Zhangb  and  Thomas C. W. Mak*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China
E-mail: tcwmak@cuhk.edu.hk
Fax: +852 2603-5057

b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, P. R. China

Abstract

A convenient new synthesis of trans-Ru(CO)3(μ-L)2 [L = 2-(diphenylphosphino)pyridine, N-(diphenylphosphinomethyl)morpholine)] was developed. The reactions of these two tridentate organometallic ligands with selected group 11 and 12 metal salts resulted in the formation of hetero-binuclear Ru0 → Mn+ [M = Ag(I), n = 1; Hg(II), Cd(II), n = 2] complexes with Ru–Ag = 2.7132(7) Å, Ru–Hg = 2.7075(4) Å and Ru–Cd = 2.7750(9) Å, as determined by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/B108287F
Article type
Paper
Submitted
11 Sep 2001
Accepted
05 Oct 2001
First published
09 Jan 2002

New J. Chem., 2002,26, 113-119

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Hetero-binuclear complexes containing a Ru0 → Mn+ bond bridged by P,N-phosphine ligands: convenient synthesis of tridentate organometallic trans-Ru(CO)3(L)2  (L = phosphine bearing an N-donor substituent) ligands

H. Song, Z. Zhang and T. C. W. Mak, New J. Chem., 2002, 26, 113 DOI: 10.1039/B108287F

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