Issue 4, 2002
From the journal:

Mendeleev Communications

Diastereoselective cycloalkylation of diphenylphosphorylacetonitrile by α,ψ-dibromoalkanes

Natalya M. Vinogradova,*a   Irina L. Odinets,a   Konstantin A. Lyssenko,a   Alexander A. Korlyukov,a   Pavel V. Petrovskii,a   Gerd V. Roeschenthalerb  and  Tatyana A. Mastryukovaa  

* Corresponding authors

a A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation, ul. Vavilova, 28, Moscow, Russian Federation
E-mail: mastr@ineos.ac.ru

b Institut fuer Anorganische und Physikalische Chemie, Universitaet Bremen, Bremen, Germany, Leobener Strasse, Bremen, Germany

Abstract

Cycloalkylation of Ph2P(O)CH2CN 1 by α,ψ-dibromoalkanes under phase-transfer catalysis conditions (K2CO3/DMSO) proceeds diastereoselectively yielding (1RS,2RS)-1-(diphenylphosphoryl)-2-methylcycloalkane carbonitriles 2.

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Article information

DOI
https://doi.org/10.1070/MC2002v012n04ABEH001613
Article type
Paper
Submitted
06 Jun 2002

Mendeleev Commun., 2002,12, 133-135

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Diastereoselective cycloalkylation of diphenylphosphorylacetonitrile by α,ψ-dibromoalkanes

N. M. Vinogradova, I. L. Odinets, K. A. Lyssenko, A. A. Korlyukov, P. V. Petrovskii, G. V. Roeschenthaler and T. A. Mastryukova, Mendeleev Commun., 2002, 12, 133 DOI: 10.1070/MC2002v012n04ABEH001613

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