Issue 4, 2002
From the journal:

Mendeleev Communications

Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

Ivan S. Orlov,a   Anna A. Moiseeva,b   Kim P. Butin,b   Lawrence R. Sita,c   Mikhail P. Egorova  and  Oleg M. Nefedova  

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation, Leninsky prospekt, 47, Moscow, Russian Federation

b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation, Leninskie Gory, Moscow, Russian Federation

c Department of Chemistry and Biochemistry, University of Maryland, Maryland, USA, College Park, Maryland, United States of America

Abstract

The radical anion of di(2,6-diethylphenyl)stannylene (Ar2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar2Sn)3, and the electrochemical oxidation of cyclo-(Ar2Sn)3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.

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Article information

DOI
https://doi.org/10.1070/MC2002v012n04ABEH001601
Article type
Paper
Submitted
29 Apr 2002

Mendeleev Commun., 2002,12, 125-126

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Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

I. S. Orlov, A. A. Moiseeva, K. P. Butin, L. R. Sita, M. P. Egorov and O. M. Nefedov, Mendeleev Commun., 2002, 12, 125 DOI: 10.1070/MC2002v012n04ABEH001601

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