Issue 3, 2002

Novel selective acid-catalysed rearrangement of the carane-typeα-(N-acylamino)oximes: the X-ray structure of (1S,5S)-1-isopropyl-3,5-dimethyl-2-oxa-4-azabicyclo[3.3.1]non-3-en-6-one (E)-oxime

Abstract

The acid-catalysed rearrangement of carane-typeα-(N-acylamino)oximes results in the formation of new bridged heterocycles with the 3-substituted 1-isopropyl-6-hydroxyimino-3-methyl-2-oxa-4-azabicyclo[3.3.1]non-3-ene skeleton.

Article information

Article type
Paper

Mendeleev Commun., 2002,12, 88-89

Novel selective acid-catalysed rearrangement of the carane-typeα-(N-acylamino)oximes: the X-ray structure of (1S,5S)-1-isopropyl-3,5-dimethyl-2-oxa-4-azabicyclo[3.3.1]non-3-en-6-one (E)-oxime

A. M. Agafontsev, T. V. Rybalova, Y. V. Gatilov and A. V. Tkachev, Mendeleev Commun., 2002, 12, 88 DOI: 10.1070/MC2002v012n03ABEH001607

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