Isokinetic relationship for nucleophilic substitution reactions with a participating thiosulfate ion in aqueous-organic media: a special reaction mechanism

Abstract

For 72 nucleophilic substitution reactions at a saturated carbon atom with the participation of the S ₂ O ₃ ^2– anion in aqueous-organic media, an isokinetic relationship withT _iso = 1130 K and lg k _iso = 5.949 was found.