High hole mobilities in carbazole-based glass-forming hydrazones

Abstract

The properties of a series of carbazole-based dihydrazones are reported. The dependence of their thermal and glass-forming properties on their chemical structure is discussed. The hydrazones having phenyl substituents at the N atom of the hydrazine moiety form glasses and their amorphous films on the glass or polyester substrates can be prepared by casting from solutions. The ionization potentials of the synthesized hydrazones measured by the electron photoemission technique range from 5.24 to 5.50 eV. Hole drift mobilities of some newly synthesized carbazole-based dihydrazones appproach 10⁻² cm² V⁻¹ s⁻¹ at an electric field of 6.4×10⁵ V cm⁻¹, at 22 °C.