Issue 5, 2002

Abstract

Two compounds i.e. (S)-N-(2-methylbutyl)-4-[(4′-undecyloxybiphenyl-4-yl)oxycarbonyl]phthalimide and (S)-N-(1-methylpropyl)-4-[(4′-undecyloxybiphenyl-4-yl)oxycarbonyl]phthalimide were synthesised from chiral components (S)-2-methylbutan-1-ol and (S)-2-aminobutane, respectively. Then, the obtained ester imides were treated with Lawesson's reagent yielding monothio- and dithioimides. Liquid crystalline smectic C* phases occurred in all imides and thioimides studied.

Graphical abstract: Synthesis and liquid crystalline properties of monothio- and dithioimides with chiral N-substituents

Article information

Article type
Paper
Submitted
13 Dec 2001
Accepted
12 Feb 2002
First published
14 Mar 2002

J. Mater. Chem., 2002,12, 1311-1315

Synthesis and liquid crystalline properties of monothio- and dithioimides with chiral N-substituents

D. Melon-Ksyta, A. Orzeszko, W. Borys and K. Czupryński, J. Mater. Chem., 2002, 12, 1311 DOI: 10.1039/B111391G

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