Issue 4, 2002
From the journal:

Journal of Materials Chemistry

Zhengbo Han,a   Enbo Wang,*a   Guoyou Luan,a   Yangguang Li,a   Hong Zhang,a   Yingbo Duan,b   Changwen Hua  and  Ninghai Huc  

* Corresponding authors

a Department of Chemistry, Northeast Normal University, Changchun, P. R. China
E-mail: wangenbo@public.cc.jl.cn

b Northeast General Pharmaceutical Factory, Shenyang, P. R. China

c Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, P. R. China

Abstract

The first heteropoly acid–dipeptide complex, (HGly-Gly)3PMo12O40·4H2O, was synthesized and characterized by elemental analysis, IR, UV, 1H NMR and single crystal X-ray diffraction. The X-ray crystallographic study showed that the crystal structure was constructed from N–H⋯O and O–H⋯O hydrogen bonds among the (HGly-Gly)+, H2O and PMo12O403− units. This structure represents a model interaction between polyoxometalates and proteins. The complex has photosensitivity under irradiation by sunlight. The fluorescent activity of this compound is also reported.

Graphical abstract: Synthesis, properties and structural characterization of an intermolecular photosensitive complex: (HGly-Gly)3PMo12O40·4H2O

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Article information

DOI
https://doi.org/10.1039/B107225K
Article type
Paper
Submitted
09 Aug 2001
Accepted
24 Jan 2002
First published
20 Feb 2002

J. Mater. Chem., 2002,12, 1169-1173

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Synthesis, properties and structural characterization of an intermolecular photosensitive complex: (HGly-Gly)3PMo12O40·4H2O

Z. Han, E. Wang, G. Luan, Y. Li, H. Zhang, Y. Duan, C. Hu and N. Hu, J. Mater. Chem., 2002, 12, 1169 DOI: 10.1039/B107225K

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