Issue 1, 2002

Abstract

The magnetic properties of scheelite related compounds AgLnMo2O8 (Ln = lanthanide) are reported. Magnetic susceptibility measurements show that the compounds are paramagnetic down to 2 K with AgSmMo2O8 and AgEuMo2O8 showing Van Vleck paramagnetism. A 151Eu Mössbauer spectrum for AgEuMo2O8 indicates that the Eu ion is in the trivalent state and that an axial electric field gradient exists in this compound. Both magnetic susceptibility and electron paramagnetic resonance (EPR) measurements show that the Gd3+ ion is in the 8S7/2 state.

Graphical abstract: Magnetic properties of silver lanthanide molybdates AgLnMo2O8 (Ln = lanthanide)

Article information

Article type
Paper
Submitted
13 Jun 2001
Accepted
12 Oct 2001
First published
27 Nov 2001

J. Mater. Chem., 2002,12, 148-152

Magnetic properties of silver lanthanide molybdates AgLnMo2O8 (Ln = lanthanide)

N. Taira and Y. Hinatsu, J. Mater. Chem., 2002, 12, 148 DOI: 10.1039/B105179M

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