Issue 6, 2002

Clean synthesis of F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols

Abstract

The addition reactions of F-carboxylic acids to terminal and cyclic olefins and of F-alkanoyl halides to cyclic ethers has been found to be useful for preparing F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols, respectively. Both types of reaction can be performed under solvent-free conditions and no accompanying by-products are formed; in some cases a 100% atom efficiency was achieved.

Graphical abstract: Clean synthesis of F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols

Article information

Article type
Paper
Submitted
23 Jul 2002
First published
21 Oct 2002

Green Chem., 2002,4, 595-598

Clean synthesis of F-carboxylic esters of sec-alcohols and ω-haloalkyl alcohols

T. Taniguchi, E. Hayashi and T. Ono, Green Chem., 2002, 4, 595 DOI: 10.1039/B207215G

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