Issue 21, 2002

A simple, general synthesis of mixed d–f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(β-diketonate) luminophores linked by bis-diimine bridging ligands

Abstract

Reaction of the mononuclear ‘complex ligands’ [Re(CO)3Cl(L)] [L = 2,2′-bipyrimidine (bpym) or 2,3-bis(2-pyridyl)pyrazine (bppz)] with a Ln(β-diketonate)3 unit affords the heterodinuclear complexes [Re(CO)3Cl(μ-bpym)Ln(fod)3] and [Re(CO)3Cl(μ-bppz)Ln(tta)3]; one member of each series has been structurally characterised.

Graphical abstract: A simple, general synthesis of mixed d–f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(β-diketonate) luminophores linked by bis-diimine bridging ligands

Supplementary files

Article information

Article type
Communication
Submitted
09 Aug 2002
Accepted
02 Oct 2002
First published
11 Oct 2002

J. Chem. Soc., Dalton Trans., 2002, 3925-3927

A simple, general synthesis of mixed d–f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(β-diketonate) luminophores linked by bis-diimine bridging ligands

N. M. Shavaleev, Z. R. Bell and M. D. Ward, J. Chem. Soc., Dalton Trans., 2002, 3925 DOI: 10.1039/B207832E

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