Issue 23, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Supramolecular assemblies of p-sulfonatocalix[4]arene with aquated trivalent lanthanide ions

Jerry L. Atwood,b   Leonard J. Barbour,b   Scott Dalgarno,a   Colin L. Raston*a  and  Helen R. Webbc  

* Corresponding authors

a Department of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK
E-mail: C.L.Raston@chemistry.leeds.ac.uk, clraston@chem.uwa.edu.au

b Department of Chemistry, University of Missouri – Columbia, Columbia, Missouri 65211, USA

c School of Chemistry, Monash University, Clayton, Victoria, 3800, Australia

Abstract

New structural motifs incorporating trivalent lanthanoid ions and p-sulfonatocalix[4]arene, derived from solutions with or without potential host molecules for the calixarene, notably 18-crown-6, 1-aza-18-crown-6, and cryptand[2.2.2], have been authenticated. These include coordination polymers which form bi-layer sheet structures and an unprecedented combined ‘ferris wheel’ and ‘molecular capsule’ structure for Ce3+ which incorporates two previously reported structural motifs associated with this type of chemistry, respectively for elements to the left and right of cerium in the lanthanide series.

Graphical abstract: Supramolecular assemblies of p-sulfonatocalix[4]arene with aquated trivalent lanthanide ions

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Article information

DOI
https://doi.org/10.1039/B206129E
Article type
Paper
Submitted
26 Jun 2002
Accepted
24 Sep 2002
First published
31 Oct 2002

J. Chem. Soc., Dalton Trans., 2002, 4351-4356

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Supramolecular assemblies of p-sulfonatocalix[4]arene with aquated trivalent lanthanide ions

J. L. Atwood, L. J. Barbour, S. Dalgarno, C. L. Raston and H. R. Webb, J. Chem. Soc., Dalton Trans., 2002, 4351 DOI: 10.1039/B206129E

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