Issue 14, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Hydrothermal synthesis and crystal structure of a hybrid material based on [Co4(phen)8(H2O)2(HPO3)2]4+ and a highly reduced polyoxoanion

Mei Yuan,a   Yangguang Li,a   Enbo Wang,*ab   Ying Lu,a   Changwen Hu,a   Ninghai Huc  and  Hengqing Jiac  

* Corresponding authors

a Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China
E-mail: wangenbo@public.cc.jl.cn

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China

c Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, P. R. China

Abstract

An unusual composite hybrid material [Co4(phen)8(H2O)2(HPO3)2](H3O)3[PMoVI8VIV4O40(VIVO)2] 1 (phen = 1,10-phenanthroline) has been hydrothermally synthesized from a mixture of NH4VO3, Na2MoO4·2H2O, CoCl2·6H2O, phen, H3PO3 and water. It was characterized by elemental analysis, IR, UV-vis, XPS, EPR, TG and single crystal X-ray diffraction. The title compound is constructed from the organic–inorganic hybrid [Co4(phen)8(H2O)2(HPO3)2]4+ and highly reduced bi-capped pseudo-Keggin [PMoVI8VIV4O40(VIVO)2]7− polyoxoanions The structure exhibits an extended 2D network through hydrogen bonds among cations, anions and H2O, combining polyoxometalates with metal phosphonates for the first time.

Graphical abstract: Hydrothermal synthesis and crystal structure of a hybrid material based on [Co4(phen)8(H2O)2(HPO3)2]4+ and a highly reduced polyoxoanion

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B203737H
Article type
Paper
Submitted
17 Apr 2002
Accepted
17 May 2002
First published
21 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2916-2920

Permissions

Request permissions

Hydrothermal synthesis and crystal structure of a hybrid material based on [Co4(phen)8(H2O)2(HPO3)2]4+ and a highly reduced polyoxoanion

M. Yuan, Y. Li, E. Wang, Y. Lu, C. Hu, N. Hu and H. Jia, J. Chem. Soc., Dalton Trans., 2002, 2916 DOI: 10.1039/B203737H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements