Issue 13, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Seven-coordinated scandium(iii) chloroions in ScCl3–CsCl molten mixtures at 600–900 °C

Georgia D. Zissia  and  George N. Papatheodorou*a  

* Corresponding authors

a Institute of Chemical Engineering and High Temperature Chemical Processes - FORTH and Department of Chemical Engineering, University of Patras, P.O.Box 1414, Patras, GR-26500, Greece

Abstract

Raman spectroscopic measurements of ScCl3–CsCl molten mixtures in the temperature range of 600–900 °C and compositions up to 25 mol% ScCl3 indicate that the predominant scandium(III) chloroions in these melts are ScCl3−6 and a novel all chloride highly coordinated ScCl4−7.

Graphical abstract: Seven-coordinated scandium(iii) chloroions in ScCl3–CsCl molten mixtures at 600–900 °C

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Article information

DOI
https://doi.org/10.1039/B203339A
Article type
Communication
Submitted
04 Apr 2002
Accepted
28 May 2002
First published
10 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2599-2600

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Seven-coordinated scandium(III) chloroions in ScCl3–CsCl molten mixtures at 600–900 °C

G. D. Zissi and G. N. Papatheodorou, J. Chem. Soc., Dalton Trans., 2002, 2599 DOI: 10.1039/B203339A

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