Issue 15, 2002

Hydrothermal synthesis and crystal structure of a layered vanadium phosphate with a directly coordinated organonitrogen ligand: [V4O7(HPO4)2(2,2′-bipy)2]

Abstract

A layered vanadium phosphate [V4O7(HPO4)2(2,2′-bipy)2] was synthesized and characterized (elemental analysis, IR and thermal analysis) by the hydrothermal reaction of NaVO3·2H2O, ZnO, H3PO4, 2,2′-bipy and water. The compound [V4O7(HPO4)2(2,2′-bipy)2] exhibits a unique 4,6,8-net structure with organonitrogen donors of 2,2′-bipy ligands coordinated directly to the vanadium phosphate framework.

Graphical abstract: Hydrothermal synthesis and crystal structure of a layered vanadium phosphate with a directly coordinated organonitrogen ligand: [V4O7(HPO4)2(2,2′-bipy)2]

Supplementary files

Article information

Article type
Paper
Submitted
04 Apr 2002
Accepted
11 Jun 2002
First published
11 Jul 2002

J. Chem. Soc., Dalton Trans., 2002, 3029-3031

Hydrothermal synthesis and crystal structure of a layered vanadium phosphate with a directly coordinated organonitrogen ligand: [V4O7(HPO4)2(2,2′-bipy)2]

Y. Lu, E. Wang, M. Yuan, G. Luan, Y. Li, H. Zhang, C. Hu, Y. Yao, Y. Qin and Y. Chen, J. Chem. Soc., Dalton Trans., 2002, 3029 DOI: 10.1039/B203324K

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