Issue 3, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

The systematic generation of monodentate bridging ethanoates in dinuclear nickel(ii) complexes of asymmetric compartmental ligands†

Harry Adams,a   Scott Clunas,a   David E. Fenton*a  and  Sharon E. Speya  

* Corresponding authors

a Department of Chemistry, The University of Sheffield, Dainton Building, Brook Hill, Sheffield, UK
E-mail: d.fenton@sheffield.ac.uk

Abstract

The presence of five-membered chelating rings derived from the iminic and aminic pendant arms in dinuclear nickel(II) complexes of asymmetric compartmental ligands gives rise to syn–syn bidentate ethanoate bridging in these complexes whereas the introduction of a six-membered chelating ring at the iminic binding site induces an ethanoate shift generating a monodentate bridging ethanoate group.

Graphical abstract: The systematic generation of monodentate bridging ethanoates in dinuclear nickel(ii) complexes of asymmetric compartmental ligands

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B107928J
Article type
Paper
Submitted
03 Sep 2001
Accepted
21 Nov 2001
First published
11 Jan 2002

J. Chem. Soc., Dalton Trans., 2002, 441-448

Permissions

Request permissions

The systematic generation of monodentate bridging ethanoates in dinuclear nickel(II) complexes of asymmetric compartmental ligands

H. Adams, S. Clunas, D. E. Fenton and S. E. Spey, J. Chem. Soc., Dalton Trans., 2002, 441 DOI: 10.1039/B107928J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements