{FeCl[tBuN(SiMe2)]2O}2: The first multinuclear iron(III) complex exhibiting spin-admixture

Garry Mund; Raymond J. Batchelor; Rajendra D. Sharma; Colin H. W. Jones; Daniel B. Leznoff

doi:10.1039/B106621H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

{FeCl[^tBuN(SiMe₂)]₂O}₂: The first multinuclear iron(iii) complex exhibiting spin-admixture

Garry Mund,^a Raymond J. Batchelor,^a Rajendra D. Sharma,^a Colin H. W. Jones^a and Daniel B. Leznoff*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, B.C. V5A 1S6 Canada
E-mail: dleznoff@sfu.ca

Abstract

The first iron(III) complexes with a chelating diamido ligand, {FeX[^tBuN(SiMe₂)]₂O}₂ (X = Cl, Br), form halide-bridged dimers in which each iron(III) centre exhibits 3/2, 5/2 quantum spin admixture; the two metals show weak antiferromagnetic coupling.

Download options Please wait...

Supplementary files

Crystal structure data TXT (22K)

Article information

DOI: https://doi.org/10.1039/B106621H
Article type: Communication
Submitted: 23 Jul 2001
Accepted: 12 Nov 2001
First published: 12 Dec 2001

Download Citation

J. Chem. Soc., Dalton Trans., 2002, 136-137

Permissions

Request permissions

{FeCl[^tBuN(SiMe₂)]₂O}₂: The first multinuclear iron(III) complex exhibiting spin-admixture

G. Mund, R. J. Batchelor, R. D. Sharma, C. H. W. Jones and D. B. Leznoff, J. Chem. Soc., Dalton Trans., 2002, 136 DOI: 10.1039/B106621H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Fetching data from CrossRef.
This may take some time to load.

Journal of the Chemical Society, Dalton Transactions